Preparation and Investigation of coumarin-based chemosensors towards sensing of ions using UV studies in aqueous systems
- Authors: Kotze, Tyla
- Date: 2024-04
- Subjects: Chemistry, Analytic , Water chemistry , Ionic solutions , Aquatic ecology , Geochemistry
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/64116 , vital:73654
- Description: Humanity's unrelenting expansion has shown little regard for the environment, and this has resulted in tons of toxic heavy metal cations and anions being released into the environment through industrial, agricultural, electronic, and mining dumping. The release of these toxic heavy metals can cause diseases and sometimes lead to death, especially in third-world countries with low-income that reside in informal settlements, who suffer the most. Furthermore, the release of these toxins eventually finds their way back into the environment through bioaccumulation in fish, plants and animals. Although there is an ever need for the growth of these industries; low-cost, sensitive, selective, and organic-based sensors is a positive step forward in highlighting the need for environmental restoration and remediation, whilst striving to avoid unnecessary disease and death through this development. In this project, coumarin-based chemosensors for the detection of cationic and anionic species in aqueous and organic media are described. This project involves the synthesis of six different coumarin-based ether derivatives (E2-E5) and coumarin-based ester derivatives (H1-H2). FT-IR, 1H NMR and 13C NMR were used to confirm the structures of all sensors. The abilities of these novel compounds as chemosensors for detection of cations and anions were investigated using UV-vis analysis. These compounds displayed a favourable interaction with Fe2+ and Fe3+ ions with an increase in absorbance. Ether derivatives E2-E5 did not display any degree of selectivity or sensitivity towards the chosen anions. It was found that in the presence of FeCl2, sensors H1 and H2 displayed a degree of selectivities and further investigations were therefore carried out. From the titration experiments, the limit of detection, limit of quantification and association constants were determined. Job’s plot analyses were performed to determine the binding ratios, which was supported by Benesi-Hildebrand studies. The binding ratio between the sensors and metal cations during complexation was found to be 1:1. Reversibility studies were carried out using EDTA to determine whether the sensors could be reused. Molecular Modelling studies were used to determine the most preferred binding sites. Lastly, real-life application screenings were also run to determine if the sensors will be able to be used in real-life scenarios. , Thesis (MSc) -- Faculty of Science, School of Biomolecular & Chemical Sciences, 2024
- Full Text:
- Date Issued: 2024-04
- Authors: Kotze, Tyla
- Date: 2024-04
- Subjects: Chemistry, Analytic , Water chemistry , Ionic solutions , Aquatic ecology , Geochemistry
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/64116 , vital:73654
- Description: Humanity's unrelenting expansion has shown little regard for the environment, and this has resulted in tons of toxic heavy metal cations and anions being released into the environment through industrial, agricultural, electronic, and mining dumping. The release of these toxic heavy metals can cause diseases and sometimes lead to death, especially in third-world countries with low-income that reside in informal settlements, who suffer the most. Furthermore, the release of these toxins eventually finds their way back into the environment through bioaccumulation in fish, plants and animals. Although there is an ever need for the growth of these industries; low-cost, sensitive, selective, and organic-based sensors is a positive step forward in highlighting the need for environmental restoration and remediation, whilst striving to avoid unnecessary disease and death through this development. In this project, coumarin-based chemosensors for the detection of cationic and anionic species in aqueous and organic media are described. This project involves the synthesis of six different coumarin-based ether derivatives (E2-E5) and coumarin-based ester derivatives (H1-H2). FT-IR, 1H NMR and 13C NMR were used to confirm the structures of all sensors. The abilities of these novel compounds as chemosensors for detection of cations and anions were investigated using UV-vis analysis. These compounds displayed a favourable interaction with Fe2+ and Fe3+ ions with an increase in absorbance. Ether derivatives E2-E5 did not display any degree of selectivity or sensitivity towards the chosen anions. It was found that in the presence of FeCl2, sensors H1 and H2 displayed a degree of selectivities and further investigations were therefore carried out. From the titration experiments, the limit of detection, limit of quantification and association constants were determined. Job’s plot analyses were performed to determine the binding ratios, which was supported by Benesi-Hildebrand studies. The binding ratio between the sensors and metal cations during complexation was found to be 1:1. Reversibility studies were carried out using EDTA to determine whether the sensors could be reused. Molecular Modelling studies were used to determine the most preferred binding sites. Lastly, real-life application screenings were also run to determine if the sensors will be able to be used in real-life scenarios. , Thesis (MSc) -- Faculty of Science, School of Biomolecular & Chemical Sciences, 2024
- Full Text:
- Date Issued: 2024-04
Field mapping and geochemistry of lower Jurassic sediments and volcanics of the upper Karoo supergroup near Ha Mosi, Lesotho mountains
- Authors: Valashiya, Khaya
- Date: 2023-12
- Subjects: Sediments (Geology) -- South Africa -- karoo basin , Geochemistry , Geological mapping
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/62687 , vital:72925
- Description: Geological mapping in the Lesotho-Drakensberg Mountains spans over 100 years with du Toit and Stockley being the major contributors to the published maps and to the understanding of emplacement of the Karoo Large Igneous Province (KLIP) in the countries of South Africa and Lesotho. Despite the detailed previous work, there remains limited data on paleoenvironmental changes at the contact between the sedimentary and volcanic sequences of the upper Karoo Supergroup. This study aims to map the lithostratigraphic boundaries, volcano-sedimentary facies and faults near Ha Mosi in southern Lesotho. A total 48 rock samples were collected for petrography, XRF and ICP-MS analyses. The new results were used to characterize the local chemostratigraphy and to propose new regional correlations across Lesotho and South Africa. In this thesis, eight lithostratigraphic units were defined with a total thickness of 550 m. The first two units (Units 1 and 2) comprise massive and bedded sandstones, interpreted as possible floodplain and ephemeral lacustrine deposits; these are ascribed to the upper Stormberg Group. These units are unconformably overlain by locally preserved thin basaltic (Unit 3) flows that are characterised by high Zr/Nb and Zr/Y ratios; and low Ti/Zr and P/Zr ratios similar to the Golden Gate Unit of the Drakensberg Group. The lava flows are overlain by bedded sandstone ascribed to Unit 4 and volcaniclastic breccia ascribed to Units 5 and 6. Unit 6 consists of a monolithic breccia that is composed of angular sandstone clasts similar to those of the underlying Stormberg Group. The monolithic breccia transitions upwards into a massive megaclastic clast-supported volcanic breccia, which consists of angular to sub-rounded basaltic and doleritic boulders. Petrified wood fragments are found within the megaclastic breccia, indicating the presence of vegetation during deposition and enhanced preservation. Unit 6 laterally grades into Unit 5, which is characterised by poorly bedded breccia composed of angular sandstone, mudstone clasts with minor basaltic and doleritic clasts and, breccia intraclasts. The breccia units are often associated with reworked sediments interpreted to be deposited by fluvial systems. The breccia is conformably overlain by basaltic lava flows (Unit 8) characterised by high Ti/Zr and P/Zr ratios and moderate to low Zr/Y and Zr/Nb ratios compared to the Unit 3 lavas and is similar to that of the Sani Pass Unit of the Drakensberg Group. The basaltic sequences in the Ha Mosi studied area preserve both pahoehoe textures and pillow lavas, indicating subaerial and subaqueous volcanism. The studied lithologies are intruded by gabbro and dolerites of the Karoo Dolerite Suite at 183 Ma. This stratigraphy records the transition from sedimentation in the Karoo Basin through to a dominantly volcanic succession, which has importance in terms of the Toarcian extinction at ca. 182 Ma. Mapped faults and associated fractures are orientated predominantly NW-SE with the hanging walls moved maximum 80 m to the south. The different dykes and fault structures possibly relate to the Weddel Triple Junction that developed during the Early Jurassic break up of Gondwana, between 200 and 180 Ma. The mapped lavas show that the magma source was a chemically heterogenous mantle that was subjected to different degrees of partial melting, with the introduction of small-scale chemical heterogeneities. The geodynamic setting is comparable to the Afar Triangle of north-east Africa where active tectonics created a large-scale NW-SE orientated fault system in response to crustal thinning and rifting. In both the Afar and Lesotho, vertical movements created lowlands that allow for the preservation of volcanic breccia and basalts with pillow lavas. These findings show that existing geological models in the Drakensberg-Lesotho Mountains can be improved upon detailed field mapping and geochemistry. , Thesis (MSc) -- Faculty of Science, School of Environmental Sciences, 2023
- Full Text:
- Date Issued: 2023-12
- Authors: Valashiya, Khaya
- Date: 2023-12
- Subjects: Sediments (Geology) -- South Africa -- karoo basin , Geochemistry , Geological mapping
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/62687 , vital:72925
- Description: Geological mapping in the Lesotho-Drakensberg Mountains spans over 100 years with du Toit and Stockley being the major contributors to the published maps and to the understanding of emplacement of the Karoo Large Igneous Province (KLIP) in the countries of South Africa and Lesotho. Despite the detailed previous work, there remains limited data on paleoenvironmental changes at the contact between the sedimentary and volcanic sequences of the upper Karoo Supergroup. This study aims to map the lithostratigraphic boundaries, volcano-sedimentary facies and faults near Ha Mosi in southern Lesotho. A total 48 rock samples were collected for petrography, XRF and ICP-MS analyses. The new results were used to characterize the local chemostratigraphy and to propose new regional correlations across Lesotho and South Africa. In this thesis, eight lithostratigraphic units were defined with a total thickness of 550 m. The first two units (Units 1 and 2) comprise massive and bedded sandstones, interpreted as possible floodplain and ephemeral lacustrine deposits; these are ascribed to the upper Stormberg Group. These units are unconformably overlain by locally preserved thin basaltic (Unit 3) flows that are characterised by high Zr/Nb and Zr/Y ratios; and low Ti/Zr and P/Zr ratios similar to the Golden Gate Unit of the Drakensberg Group. The lava flows are overlain by bedded sandstone ascribed to Unit 4 and volcaniclastic breccia ascribed to Units 5 and 6. Unit 6 consists of a monolithic breccia that is composed of angular sandstone clasts similar to those of the underlying Stormberg Group. The monolithic breccia transitions upwards into a massive megaclastic clast-supported volcanic breccia, which consists of angular to sub-rounded basaltic and doleritic boulders. Petrified wood fragments are found within the megaclastic breccia, indicating the presence of vegetation during deposition and enhanced preservation. Unit 6 laterally grades into Unit 5, which is characterised by poorly bedded breccia composed of angular sandstone, mudstone clasts with minor basaltic and doleritic clasts and, breccia intraclasts. The breccia units are often associated with reworked sediments interpreted to be deposited by fluvial systems. The breccia is conformably overlain by basaltic lava flows (Unit 8) characterised by high Ti/Zr and P/Zr ratios and moderate to low Zr/Y and Zr/Nb ratios compared to the Unit 3 lavas and is similar to that of the Sani Pass Unit of the Drakensberg Group. The basaltic sequences in the Ha Mosi studied area preserve both pahoehoe textures and pillow lavas, indicating subaerial and subaqueous volcanism. The studied lithologies are intruded by gabbro and dolerites of the Karoo Dolerite Suite at 183 Ma. This stratigraphy records the transition from sedimentation in the Karoo Basin through to a dominantly volcanic succession, which has importance in terms of the Toarcian extinction at ca. 182 Ma. Mapped faults and associated fractures are orientated predominantly NW-SE with the hanging walls moved maximum 80 m to the south. The different dykes and fault structures possibly relate to the Weddel Triple Junction that developed during the Early Jurassic break up of Gondwana, between 200 and 180 Ma. The mapped lavas show that the magma source was a chemically heterogenous mantle that was subjected to different degrees of partial melting, with the introduction of small-scale chemical heterogeneities. The geodynamic setting is comparable to the Afar Triangle of north-east Africa where active tectonics created a large-scale NW-SE orientated fault system in response to crustal thinning and rifting. In both the Afar and Lesotho, vertical movements created lowlands that allow for the preservation of volcanic breccia and basalts with pillow lavas. These findings show that existing geological models in the Drakensberg-Lesotho Mountains can be improved upon detailed field mapping and geochemistry. , Thesis (MSc) -- Faculty of Science, School of Environmental Sciences, 2023
- Full Text:
- Date Issued: 2023-12
Lateral and vertical mineral-chemical variation in high-grade ores of the Kalahari Manganese Field, and implications for ore genesis and geometallurgy
- Authors: Motilaodi, Donald
- Date: 2022-10-14
- Subjects: Manganese ores , Geometallurgy , Hydrothermal alteration , Petrology , Mineralogy , Geochemistry
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362972 , vital:65379
- Description: The Kalahari Manganese Field (KMF) is a world-class resource of manganese ore hosted by the Paleoproterozoic Hotazel banded iron formation. KMF ores are categorised into two main types, i.e., low-grade, carbonate rich, braunitic ore (Mn≤40wt%) and carbonate-free, high-grade, Ca-braunite+hausmannite ore (Mn≥44wt%). High-grade ores, also known as Wessels type from the homonymous mine in the northernmost KMF, are thought to have formed from variable degrees of hydrothermal carbonate and silica leaching from a low-grade ore precursor, termed Mamatwan-type after the homonymous mine in the southernmost KMF. This project aims to conduct a mineralogical and mineral-chemical study of representative manganese ore samples from a suite of drillcores intersecting both the upper and the lower layers in the northern KMF, covering the areas of Wessels, N’chwaning and Gloria mines. Petrographically, the high-grade Mn ore displays great variability in three-dimensional space. Texturally, the ores exhibit a great variety of textures which may or may not show preservation of the laminated and ovoidal textures that typify the postulated low-grade protore. There is also significant variation in the mineralogical and geochemical characteristics of the high-grade Mn ores both vertically and laterally. Vertical variation includes, probably for the first time, variability between the upper and lower ore layers within individual drillcores of the Hotazel sequence. Mineralogically, the ores contain variable modal abundances of the ore-forming minerals braunite (I, II, “new”) and hausmannite, and much less so of bixbyite, marokite and manganite. Common accessories include andradite, barite and low-Mn carbonate minerals. Chemically, the dominant ore minerals braunite and hausmannite, contain Fe up to 22 and 15wt% respectively, which accounts for the bulk of the iron contained in the ores. Braunite compositions also exhibit a large range with respect to their ratio of Ca/Si. Mineral-specific trace element concentrations for the same minerals measured by LA-ICP-MS, reveal generally large variations from one element to the other. When normalized against the trace element composition of bulk low-grade precursor ore, strong enrichments are recorded for both hausmannite and braunite in selected alkali/alkali earth elements, transition metals and lanthanides, such as Sc, Co, Zn, Cu, Pb, La, and Ce. These are akin to enrichments recorded in average high-grade ore. Although there is also no obvious relationship between Fe content in both hausmannite and braunite and their trace element abundances, the drillcore that captures high-grade ore with the highest trace element concentrations appears to be located most proximal to a major fault. Results collectively suggest that high-grade Mn ores of the KMF have undergone a complex hydrothermal history with a clear and significant metasomatic addition of trace elements into ore-forming minerals. First order trends in the mineralogical and mineral-chemical distribution of the ores in space, suggest hausmannite-dominated ores near the Hotazel suboutcrop, and an apparent decline in ore quality with braunite II-andradite-barite-calcite ores as the major graben fault is approached in a southwesterly direction. The latter trend appears to be at odds with prevailing fault-controlled alteration models. Elucidating that hydrothermal history of the Wessels-type high grade Mn ores of the KMF, will be crucial to understanding the compositional controls of these ores in space, and the potential impact thereof in terms of geometallurgy. , Thesis (MSc) -- Faculty of Science, Geology, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Motilaodi, Donald
- Date: 2022-10-14
- Subjects: Manganese ores , Geometallurgy , Hydrothermal alteration , Petrology , Mineralogy , Geochemistry
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362972 , vital:65379
- Description: The Kalahari Manganese Field (KMF) is a world-class resource of manganese ore hosted by the Paleoproterozoic Hotazel banded iron formation. KMF ores are categorised into two main types, i.e., low-grade, carbonate rich, braunitic ore (Mn≤40wt%) and carbonate-free, high-grade, Ca-braunite+hausmannite ore (Mn≥44wt%). High-grade ores, also known as Wessels type from the homonymous mine in the northernmost KMF, are thought to have formed from variable degrees of hydrothermal carbonate and silica leaching from a low-grade ore precursor, termed Mamatwan-type after the homonymous mine in the southernmost KMF. This project aims to conduct a mineralogical and mineral-chemical study of representative manganese ore samples from a suite of drillcores intersecting both the upper and the lower layers in the northern KMF, covering the areas of Wessels, N’chwaning and Gloria mines. Petrographically, the high-grade Mn ore displays great variability in three-dimensional space. Texturally, the ores exhibit a great variety of textures which may or may not show preservation of the laminated and ovoidal textures that typify the postulated low-grade protore. There is also significant variation in the mineralogical and geochemical characteristics of the high-grade Mn ores both vertically and laterally. Vertical variation includes, probably for the first time, variability between the upper and lower ore layers within individual drillcores of the Hotazel sequence. Mineralogically, the ores contain variable modal abundances of the ore-forming minerals braunite (I, II, “new”) and hausmannite, and much less so of bixbyite, marokite and manganite. Common accessories include andradite, barite and low-Mn carbonate minerals. Chemically, the dominant ore minerals braunite and hausmannite, contain Fe up to 22 and 15wt% respectively, which accounts for the bulk of the iron contained in the ores. Braunite compositions also exhibit a large range with respect to their ratio of Ca/Si. Mineral-specific trace element concentrations for the same minerals measured by LA-ICP-MS, reveal generally large variations from one element to the other. When normalized against the trace element composition of bulk low-grade precursor ore, strong enrichments are recorded for both hausmannite and braunite in selected alkali/alkali earth elements, transition metals and lanthanides, such as Sc, Co, Zn, Cu, Pb, La, and Ce. These are akin to enrichments recorded in average high-grade ore. Although there is also no obvious relationship between Fe content in both hausmannite and braunite and their trace element abundances, the drillcore that captures high-grade ore with the highest trace element concentrations appears to be located most proximal to a major fault. Results collectively suggest that high-grade Mn ores of the KMF have undergone a complex hydrothermal history with a clear and significant metasomatic addition of trace elements into ore-forming minerals. First order trends in the mineralogical and mineral-chemical distribution of the ores in space, suggest hausmannite-dominated ores near the Hotazel suboutcrop, and an apparent decline in ore quality with braunite II-andradite-barite-calcite ores as the major graben fault is approached in a southwesterly direction. The latter trend appears to be at odds with prevailing fault-controlled alteration models. Elucidating that hydrothermal history of the Wessels-type high grade Mn ores of the KMF, will be crucial to understanding the compositional controls of these ores in space, and the potential impact thereof in terms of geometallurgy. , Thesis (MSc) -- Faculty of Science, Geology, 2022
- Full Text:
- Date Issued: 2022-10-14
Gem-bearing granitic pegmatites in Malawi: their mineralogy, geochemistry, age, and fluid compositional variations
- Kankuzi, Charles Frienderson
- Authors: Kankuzi, Charles Frienderson
- Date: 2019
- Subjects: Granite , Pegmatites , Geochemistry , Fluid inclusions , Nonferrous metals
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/97905 , vital:31505 , DOI https://doi.org/10.21504/10962/97905
- Description: The gem bearing granitic pegmatites from different pegmatite fields across Malawi intrude all important geological entities from the Palaeoproterozoic in the north, the Mesoproterozoic in central Malawi and the Pan-African basement in the south. U/Pb zircon and Rb/Sr mineral isochron ages indicate pegmatite emplacement from the Palaeoproterozoic to Pan-African and Mesozoic time. Most pegmatites are related to the Pan-African cycle; no Mesoproterozoic pegmatites were observed in this study. Within the Pan-African pegmatite groups there are two important subgroups. Some pegmatites show Sr isotopic compositions that indicate mantle components contributing to the parental granites from which the pegmatites evolved. Others show higher Sr initials, indicating crustal granites as primary pegmatite sources or significant crustal contamination. Only for few pegmatites, such as the Palaeoproterozoic and Ordovician gem tourmaline pegmatites in the Chitipa and Dowa Districts, the granitic source is evident from their field context. For all others the granitic origin is interpreted by mineralogical and geochemical evidence. All analysed pegmatites belong to either the Rare Element Class or the Miarolitic Class, but they vary in their degree of fractionation. The more evolved pegmatites are more enriched in incompatible elements such as Be, Li, B, and Ta, which resulted in the formation of gem minerals such as beryl, aquamarine, tourmaline and topaz, which may or may not be associated with tantalite. The Rare Element pegmatites can be further subdivided into the REL-Li subclass, beryl type, beryl-columbite subtype, and in the complex type and elbaite subtype. The Miarolitic pegmatites include Mi-Li subclass and beryl-topaz type. Fluid inclusion studies (heating-cooling stage, Raman spectroscopy) identified a variety of fluid compositions that were present at different times and different places, indicating a variety of fluid sources. They range from aqueous-saline to CO2–rich carbonic fluids (CO2 +C3H8+ N2), or aqueous-carbonic fluids (H2O-CO2-CH4 and H2O-CO2-H2-H2S-CH4). The dominant solutes and species for the pegmatites show genetic variations over time and orogen (Paleo-/Meso-/Neoproterozoic). Uniform homogenisation temperatures and salinities in individual samples indicate that the gem-bearing pegmatites contained homogeneous fluids at the time of their capturing in quartz. Based on fluid inclusion data, the estimated trapping conditions of inclusions in quartz for all studied pegmatites except for one pegmatite suggest low pressures between 0.9 to 2.6 kb at temperatures of 400-600 C. The other pegmatite formed at slightly higher pressures of 2.2 to 3.6 kb. However, the pressure range for all the pegmatites is in agreement with the known liquidus conditions of Rare-Element pegmatite crystallisation. The shallow crustal emplacement level (3.4-9.8 km) and the greater depth (8.3 to 13.6 km) favoured the formation of gemstones. , Thesis (PhD) -- Faculty of Science, Geology, 2019
- Full Text: false
- Date Issued: 2019
- Authors: Kankuzi, Charles Frienderson
- Date: 2019
- Subjects: Granite , Pegmatites , Geochemistry , Fluid inclusions , Nonferrous metals
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/97905 , vital:31505 , DOI https://doi.org/10.21504/10962/97905
- Description: The gem bearing granitic pegmatites from different pegmatite fields across Malawi intrude all important geological entities from the Palaeoproterozoic in the north, the Mesoproterozoic in central Malawi and the Pan-African basement in the south. U/Pb zircon and Rb/Sr mineral isochron ages indicate pegmatite emplacement from the Palaeoproterozoic to Pan-African and Mesozoic time. Most pegmatites are related to the Pan-African cycle; no Mesoproterozoic pegmatites were observed in this study. Within the Pan-African pegmatite groups there are two important subgroups. Some pegmatites show Sr isotopic compositions that indicate mantle components contributing to the parental granites from which the pegmatites evolved. Others show higher Sr initials, indicating crustal granites as primary pegmatite sources or significant crustal contamination. Only for few pegmatites, such as the Palaeoproterozoic and Ordovician gem tourmaline pegmatites in the Chitipa and Dowa Districts, the granitic source is evident from their field context. For all others the granitic origin is interpreted by mineralogical and geochemical evidence. All analysed pegmatites belong to either the Rare Element Class or the Miarolitic Class, but they vary in their degree of fractionation. The more evolved pegmatites are more enriched in incompatible elements such as Be, Li, B, and Ta, which resulted in the formation of gem minerals such as beryl, aquamarine, tourmaline and topaz, which may or may not be associated with tantalite. The Rare Element pegmatites can be further subdivided into the REL-Li subclass, beryl type, beryl-columbite subtype, and in the complex type and elbaite subtype. The Miarolitic pegmatites include Mi-Li subclass and beryl-topaz type. Fluid inclusion studies (heating-cooling stage, Raman spectroscopy) identified a variety of fluid compositions that were present at different times and different places, indicating a variety of fluid sources. They range from aqueous-saline to CO2–rich carbonic fluids (CO2 +C3H8+ N2), or aqueous-carbonic fluids (H2O-CO2-CH4 and H2O-CO2-H2-H2S-CH4). The dominant solutes and species for the pegmatites show genetic variations over time and orogen (Paleo-/Meso-/Neoproterozoic). Uniform homogenisation temperatures and salinities in individual samples indicate that the gem-bearing pegmatites contained homogeneous fluids at the time of their capturing in quartz. Based on fluid inclusion data, the estimated trapping conditions of inclusions in quartz for all studied pegmatites except for one pegmatite suggest low pressures between 0.9 to 2.6 kb at temperatures of 400-600 C. The other pegmatite formed at slightly higher pressures of 2.2 to 3.6 kb. However, the pressure range for all the pegmatites is in agreement with the known liquidus conditions of Rare-Element pegmatite crystallisation. The shallow crustal emplacement level (3.4-9.8 km) and the greater depth (8.3 to 13.6 km) favoured the formation of gemstones. , Thesis (PhD) -- Faculty of Science, Geology, 2019
- Full Text: false
- Date Issued: 2019
A geoscientific framework for the proposed site of South Africa's second nuclear power plant: Thyspunt, Eastern Cape
- Authors: Claassen, Debbie
- Date: 2015
- Subjects: Geology, Structural -- South Africa -- Eastern Cape , Geology, Stratigraphic , Geochemistry , Rock mechanics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10678 , http://hdl.handle.net/10948/d1021182
- Description: This study describes the bedrock lithologies and structure of the Ordovician to early Devonian (485-419 Ma) Table Mountain Group (TMG), the Devonian (419-358 Ma) lower Bokkeveld Group, and the Miocene to Holocene (<23 Ma) overburden sediments of the Algoa Group within an area identified by Eskom for the potential construction of South Africa’s second proposed nuclear power plant (NPP), ‘Nuclear-1’. The study area is located along the southern coastal margin of the Eastern Cape Province, South Africa, between Oyster Bay and St. Francis (approximately 88 km west of Port Elizabeth), and encompasses the Thyspunt site where the proposed NPP will be built. The study aims to supplement existing information about the Thyspunt area, related to the geoscientific topic ‘Geological Setting’, as outlined in section 2.5.1.1 of the US Nuclear Regulatory Commission (USNRC) Standard Review Plan NUREG-800, which details the geological information required for review of a proposed NPP. The results obtained from geoscientific studies are used to determine geological factors that may potentially affect site specific design. Factors considered include: bedrock lithology, stratigraphic bedrock contacts, bedrock palaeotopography, thickness of overburden sediments and structural geology. Work by previous authors is combined with new data to create a GIS based 2½D model of the study area’s geology (geomodel) and on which future research or interpretations can be based. Field mapping and petrographic analyses of the TMG, comprising the Peninsula, Cedarberg, Goudini, Skurweberg and Baviaanskloof Formations as well as the lower undifferentiated Bokkeveld Group were undertaken to define the study area’s lithologies and structure. Interpretation of geophysical results and the integration of existing borehole data aided in defining the variability in overburden sediments, the identification of contacts between TMG formations beneath overburden, and the palaeotopography of bedrock. Borehole data indicates a clear N-S trend in the thickness distribution of Algoa Group aeolian and marine related sediments. Four coast-parallel trending thickness zones (zones A – D) are recognized within the study area. At Thyspunt overburden thickness reaches a maximum of 61 m, approximately 1200 m from the coastline, in areas underlain by the argillaceous Goudini and Cedarberg Formations. Overburden thickness is influenced by a combination of dune relief, bedrock lithology, palaeotopography and the area’s sediment supply. Interpolation of bedrock elevation points and detailed cross sections across bedrock reveals four NW-SE trending palaeovalleys at Thyspunt, Tony’s Bay, Cape St. Francis and St. Francis, where bedrock relief (beneath overburden) is formed to be below present day sea-level. Approximately 450 m NW of Thys Bay, a 1050 m2 (area below sea-level) palaeovalley, gently sloping SE to a depth of -15.5 m asl, is cut into strata of the Goudini Formation resulting in thicker overburden fill in that area. Structural analysis of the TMG confirms that NE-SW striking strata form part of the regional SE plunging, north verging Cape St. Francis anticline. Bedding inclination is controlled by the distance away from the fold axis, varying from a 5° SE dip along the broad fold hinge to 65° along its moderately steeper SE limb. Folds within the study area plunge gently southeastward at shallow angles, with axial planes dipping steeply SW or NE. Fold axes orientated perpendicular to the fold axis of the Cape St. Francis anticline indicate a secondary stress orientation oblique to the main palaeostress direction. The previously identified 40 km long, NW-SE trending Cape St. Francis fault occurring offshore within 17.5 km of Thyspunt show no onshore continuation within the bounds of the study area. Late jointing is pervasive within the study area and four joint systems are identified. The dominant joint set J1, trends N-S to NNE - SSW; perpendicular to bedding and has a subvertical dip. Normal right-lateral and left-lateral micro-faults dip subvertically, with a displacement that ranges from a few centimetres to <3 m. Micro-faults trend parallel to joints sets J1 and J4 (ESE-WSW). Inferred faults, identified by the Atomic Energy Co-operation (AEC), are interpreted as zones of closely spaced jointing (shatter zones), and show little to no recognizable displacement. Faults and joints do not extend into the younger cover deposits of the Algoa Group and are therefore older than 23 Ma years.
- Full Text:
- Date Issued: 2015
- Authors: Claassen, Debbie
- Date: 2015
- Subjects: Geology, Structural -- South Africa -- Eastern Cape , Geology, Stratigraphic , Geochemistry , Rock mechanics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10678 , http://hdl.handle.net/10948/d1021182
- Description: This study describes the bedrock lithologies and structure of the Ordovician to early Devonian (485-419 Ma) Table Mountain Group (TMG), the Devonian (419-358 Ma) lower Bokkeveld Group, and the Miocene to Holocene (<23 Ma) overburden sediments of the Algoa Group within an area identified by Eskom for the potential construction of South Africa’s second proposed nuclear power plant (NPP), ‘Nuclear-1’. The study area is located along the southern coastal margin of the Eastern Cape Province, South Africa, between Oyster Bay and St. Francis (approximately 88 km west of Port Elizabeth), and encompasses the Thyspunt site where the proposed NPP will be built. The study aims to supplement existing information about the Thyspunt area, related to the geoscientific topic ‘Geological Setting’, as outlined in section 2.5.1.1 of the US Nuclear Regulatory Commission (USNRC) Standard Review Plan NUREG-800, which details the geological information required for review of a proposed NPP. The results obtained from geoscientific studies are used to determine geological factors that may potentially affect site specific design. Factors considered include: bedrock lithology, stratigraphic bedrock contacts, bedrock palaeotopography, thickness of overburden sediments and structural geology. Work by previous authors is combined with new data to create a GIS based 2½D model of the study area’s geology (geomodel) and on which future research or interpretations can be based. Field mapping and petrographic analyses of the TMG, comprising the Peninsula, Cedarberg, Goudini, Skurweberg and Baviaanskloof Formations as well as the lower undifferentiated Bokkeveld Group were undertaken to define the study area’s lithologies and structure. Interpretation of geophysical results and the integration of existing borehole data aided in defining the variability in overburden sediments, the identification of contacts between TMG formations beneath overburden, and the palaeotopography of bedrock. Borehole data indicates a clear N-S trend in the thickness distribution of Algoa Group aeolian and marine related sediments. Four coast-parallel trending thickness zones (zones A – D) are recognized within the study area. At Thyspunt overburden thickness reaches a maximum of 61 m, approximately 1200 m from the coastline, in areas underlain by the argillaceous Goudini and Cedarberg Formations. Overburden thickness is influenced by a combination of dune relief, bedrock lithology, palaeotopography and the area’s sediment supply. Interpolation of bedrock elevation points and detailed cross sections across bedrock reveals four NW-SE trending palaeovalleys at Thyspunt, Tony’s Bay, Cape St. Francis and St. Francis, where bedrock relief (beneath overburden) is formed to be below present day sea-level. Approximately 450 m NW of Thys Bay, a 1050 m2 (area below sea-level) palaeovalley, gently sloping SE to a depth of -15.5 m asl, is cut into strata of the Goudini Formation resulting in thicker overburden fill in that area. Structural analysis of the TMG confirms that NE-SW striking strata form part of the regional SE plunging, north verging Cape St. Francis anticline. Bedding inclination is controlled by the distance away from the fold axis, varying from a 5° SE dip along the broad fold hinge to 65° along its moderately steeper SE limb. Folds within the study area plunge gently southeastward at shallow angles, with axial planes dipping steeply SW or NE. Fold axes orientated perpendicular to the fold axis of the Cape St. Francis anticline indicate a secondary stress orientation oblique to the main palaeostress direction. The previously identified 40 km long, NW-SE trending Cape St. Francis fault occurring offshore within 17.5 km of Thyspunt show no onshore continuation within the bounds of the study area. Late jointing is pervasive within the study area and four joint systems are identified. The dominant joint set J1, trends N-S to NNE - SSW; perpendicular to bedding and has a subvertical dip. Normal right-lateral and left-lateral micro-faults dip subvertically, with a displacement that ranges from a few centimetres to <3 m. Micro-faults trend parallel to joints sets J1 and J4 (ESE-WSW). Inferred faults, identified by the Atomic Energy Co-operation (AEC), are interpreted as zones of closely spaced jointing (shatter zones), and show little to no recognizable displacement. Faults and joints do not extend into the younger cover deposits of the Algoa Group and are therefore older than 23 Ma years.
- Full Text:
- Date Issued: 2015
An overview of energy minerals in the Springbok Flatsbasin, South Africa : implications for geochemical and geophysical exploration
- Authors: Ledwaba, Lebogang John
- Date: 2015
- Subjects: Energy minerals -- South Africa -- Springbok Flats (Limpopo) , Geochemistry , Prospecting -- Geophysical methods , Coal -- South Africa -- Springbok Flats (Limpopo) , Uranium -- South Africa -- Springbok Flats (Limpopo) , Coalbed methane -- South Africa -- Springbok Flats (Limpopo)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5092 , http://hdl.handle.net/10962/d1019880
- Description: This study is informed by the rising demand for power needs in South Africa and aims at understanding the geophysical and geochemical characteristics of the energy minerals in the Springbok Flats Basin and relating them to the prevailing geological and structural setting for improved exploration targeting. The Springbok Flats Basin is part of the Karoo sediments and host to uranium, coal and coal bed methane (CBM) resources. The lithology sections in the basin indicate presence of basaltic lavas at the top, underlain by mudrocks, siltstones, sandstones, conglomerates and diamictite, with interbedded coal beds occasionally. The coals are uraniferous and shale bounded and of lower Beaufort age at 250 Ma. The regional radiometric data identifies the regional extent of the Springbok Flats Basin as a basin with low total count values. This information is useful in exploration as it gives an idea of the limits of the area where to focus application for prospecting licenses. The reduced to pole of the total magnetic field, residuals and first vertical derivative maps clearly show the high magnetic susceptibility nature of the surrounding Bushveld rocks as compared to the low Karoo sediment susceptibility within the basin. There are distinct ring shaped picks within the basin possibly due to known Karoo dolerite sills in particular to the central south western part of the grid. The regional geochemical mapping program is a cost-effective way of providing an overview of the relative abundance levels, regional trends and anomalous patterns in the underlying lithological units. Background values of elements in soils over different lithological units and the identification of anomalous values relative to these elements can easily be identified. The geochemical results show an excellent correlation between soil chemistry and underlying geological formations. A few distinct gravity highs are clearly shown within the basin. Assuming the effect of the Letaba basalt to the gravity readings is uniform across the basin; these distinct anomalies could be due to Karoo dolerite sills as they coincide with areas of distinct high magnetic signature. A conceptual model was generated assuming that the Karoo sediments’ layering is uniform across the gravity profile but changes in the residual are due to an increased thickness of the sill supported by the gentle changes on the surface topography. Satellite imagery has got its challenges especially in areas of vegetation but it does provide a very useful tool in exploration. A number of spectral analysis techniques and band rations can be used to differentiate the areas underlain by the Letaba basalts, the Karoo sandstones/shale and Bushveld granites for mapping purposes. The priority focus will be on the shallower Karoo sediments because of the potential for cheaper mining. Exploration targeting needs to be guided by observed geochemical and geophysical characteristics in order to prioritize areas taking into account the presence of Karoo intrusives such as the dolerite sills that tend to devolatize the coal hence affecting the quality/rank. Structures and gravity signatures are very important in delineating areas with thick sediments that have a potential for CBM. The same understanding in targeting goes a long way in planning drill holes, resource modelling and pre-feasibility stages for mine planning. A high resolution airborne geophysical survey is recommended over the basin to better resolve structures. Geophysical borehole logging is recommended to be part of the exploration drilling programs in the Springbok Flats Basin in order to define the in-situ geophysical characteristics. Geophysical logging is useful in particular for the uranium reserves that cannot be delineated from the surface due to deep intersection.
- Full Text:
- Date Issued: 2015
- Authors: Ledwaba, Lebogang John
- Date: 2015
- Subjects: Energy minerals -- South Africa -- Springbok Flats (Limpopo) , Geochemistry , Prospecting -- Geophysical methods , Coal -- South Africa -- Springbok Flats (Limpopo) , Uranium -- South Africa -- Springbok Flats (Limpopo) , Coalbed methane -- South Africa -- Springbok Flats (Limpopo)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5092 , http://hdl.handle.net/10962/d1019880
- Description: This study is informed by the rising demand for power needs in South Africa and aims at understanding the geophysical and geochemical characteristics of the energy minerals in the Springbok Flats Basin and relating them to the prevailing geological and structural setting for improved exploration targeting. The Springbok Flats Basin is part of the Karoo sediments and host to uranium, coal and coal bed methane (CBM) resources. The lithology sections in the basin indicate presence of basaltic lavas at the top, underlain by mudrocks, siltstones, sandstones, conglomerates and diamictite, with interbedded coal beds occasionally. The coals are uraniferous and shale bounded and of lower Beaufort age at 250 Ma. The regional radiometric data identifies the regional extent of the Springbok Flats Basin as a basin with low total count values. This information is useful in exploration as it gives an idea of the limits of the area where to focus application for prospecting licenses. The reduced to pole of the total magnetic field, residuals and first vertical derivative maps clearly show the high magnetic susceptibility nature of the surrounding Bushveld rocks as compared to the low Karoo sediment susceptibility within the basin. There are distinct ring shaped picks within the basin possibly due to known Karoo dolerite sills in particular to the central south western part of the grid. The regional geochemical mapping program is a cost-effective way of providing an overview of the relative abundance levels, regional trends and anomalous patterns in the underlying lithological units. Background values of elements in soils over different lithological units and the identification of anomalous values relative to these elements can easily be identified. The geochemical results show an excellent correlation between soil chemistry and underlying geological formations. A few distinct gravity highs are clearly shown within the basin. Assuming the effect of the Letaba basalt to the gravity readings is uniform across the basin; these distinct anomalies could be due to Karoo dolerite sills as they coincide with areas of distinct high magnetic signature. A conceptual model was generated assuming that the Karoo sediments’ layering is uniform across the gravity profile but changes in the residual are due to an increased thickness of the sill supported by the gentle changes on the surface topography. Satellite imagery has got its challenges especially in areas of vegetation but it does provide a very useful tool in exploration. A number of spectral analysis techniques and band rations can be used to differentiate the areas underlain by the Letaba basalts, the Karoo sandstones/shale and Bushveld granites for mapping purposes. The priority focus will be on the shallower Karoo sediments because of the potential for cheaper mining. Exploration targeting needs to be guided by observed geochemical and geophysical characteristics in order to prioritize areas taking into account the presence of Karoo intrusives such as the dolerite sills that tend to devolatize the coal hence affecting the quality/rank. Structures and gravity signatures are very important in delineating areas with thick sediments that have a potential for CBM. The same understanding in targeting goes a long way in planning drill holes, resource modelling and pre-feasibility stages for mine planning. A high resolution airborne geophysical survey is recommended over the basin to better resolve structures. Geophysical borehole logging is recommended to be part of the exploration drilling programs in the Springbok Flats Basin in order to define the in-situ geophysical characteristics. Geophysical logging is useful in particular for the uranium reserves that cannot be delineated from the surface due to deep intersection.
- Full Text:
- Date Issued: 2015
Genesis of karst-hosted manganese ores of the Postmasburg Manganese Field, South Africa with emphasis on evidence for hydrothermal processes
- Authors: Fairey, Brenton John
- Date: 2014
- Subjects: Karst -- South Africa -- Postmasburg , Manganese ores -- South Africa -- Postmasburg , Hydrothermal alteration -- South Africa -- Postmasburg , Manganese mines and mining -- South Africa -- Northern Cape , Petrology , Mineralogical chemistry , Geochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5094 , http://hdl.handle.net/10962/d1020904
- Description: The Postmasburg Manganese Field (PMF), located in the Northern Cape Province of South Africa, once represented one of the largest sources of manganese ore worldwide. However, the discovery of the giant manganese deposits of the Kalahari Manganese Field (KMF) led to the gradual decline in manganese mining activity in the PMF. Two belts of manganese ore deposits have been distinguished in the PMF, namely the Western Belt of ferruginous manganese ores and the Eastern Belt of siliceous manganese ores. Prevailing models of ore formation in these two belts invoke karstification of manganese-rich dolomites and residual accumulation of manganese wad which later underwent diagenetic and low-grade metamorphic processes. For the most part, the role of hydrothermal processes in ore formation and metasomatic alteration is not addressed. The identification of an abundance of common and some rare Al-, Na-, K- and Ba-bearing minerals, particularly aegirine, albite, microcline, banalsite, sérandite-pectolite, paragonite and natrolite in the PMF ores studied in this thesis, is indicative of the influence of hydrothermal activity. Enrichments in Na, K and/or Ba in the ores are generally on a percentage level for the majority of samples analysed through bulk-rock techniques. The discovery of a Ba-Mn arsenate/vanadate similar to gamagarite may also indicate that the hydrothermal fluid affecting the ores was not only alkali-rich but also probably contained some As and V. The fluid was likely to be oxidized and alkaline in nature and is thought to have been a mature basinal brine. Various replacement textures, particularly of Na- and Krich minerals by Ba-bearing phases, suggest sequential deposition of gangue as well as oreminerals from the hydrothermal fluid, with Ba phases being deposited at a later stage. The stratigraphic variability of the studied ores and the deviation of their character from the pigeon-hole-type classification of ferruginous and siliceous ores in the literature, suggests that a re-evaluation of genetic models is warranted. The discovery of hydrothermallydeposited alkali-rich assemblages in the PMF and KMF provides grounding for further investigation into a possible regional-scale hydrothermal event at least re-constituting the ores. Some shortcomings in previous works include disregard for the highly variable nature of the PMF deposits, the effects of hydrothermal activity of the ores and the existence of stratigraphic discrepancies. This study provides a single, broad model for the development of all manganese deposits of the PMF. The source of metals is attributed to all formations that stratigraphically overly the Reivilo Formation of the Campbellrand Subgroup (including the Reivilo Formation itself). The main process by which metals are accumulated is attributed to karstification of the dolomites. The interaction of oxidized, alkaline brines with the ores is considered and the overlying Asbestos Hills Subgroup BIF is suggested as a potential source of alkali metals.
- Full Text:
- Date Issued: 2014
- Authors: Fairey, Brenton John
- Date: 2014
- Subjects: Karst -- South Africa -- Postmasburg , Manganese ores -- South Africa -- Postmasburg , Hydrothermal alteration -- South Africa -- Postmasburg , Manganese mines and mining -- South Africa -- Northern Cape , Petrology , Mineralogical chemistry , Geochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5094 , http://hdl.handle.net/10962/d1020904
- Description: The Postmasburg Manganese Field (PMF), located in the Northern Cape Province of South Africa, once represented one of the largest sources of manganese ore worldwide. However, the discovery of the giant manganese deposits of the Kalahari Manganese Field (KMF) led to the gradual decline in manganese mining activity in the PMF. Two belts of manganese ore deposits have been distinguished in the PMF, namely the Western Belt of ferruginous manganese ores and the Eastern Belt of siliceous manganese ores. Prevailing models of ore formation in these two belts invoke karstification of manganese-rich dolomites and residual accumulation of manganese wad which later underwent diagenetic and low-grade metamorphic processes. For the most part, the role of hydrothermal processes in ore formation and metasomatic alteration is not addressed. The identification of an abundance of common and some rare Al-, Na-, K- and Ba-bearing minerals, particularly aegirine, albite, microcline, banalsite, sérandite-pectolite, paragonite and natrolite in the PMF ores studied in this thesis, is indicative of the influence of hydrothermal activity. Enrichments in Na, K and/or Ba in the ores are generally on a percentage level for the majority of samples analysed through bulk-rock techniques. The discovery of a Ba-Mn arsenate/vanadate similar to gamagarite may also indicate that the hydrothermal fluid affecting the ores was not only alkali-rich but also probably contained some As and V. The fluid was likely to be oxidized and alkaline in nature and is thought to have been a mature basinal brine. Various replacement textures, particularly of Na- and Krich minerals by Ba-bearing phases, suggest sequential deposition of gangue as well as oreminerals from the hydrothermal fluid, with Ba phases being deposited at a later stage. The stratigraphic variability of the studied ores and the deviation of their character from the pigeon-hole-type classification of ferruginous and siliceous ores in the literature, suggests that a re-evaluation of genetic models is warranted. The discovery of hydrothermallydeposited alkali-rich assemblages in the PMF and KMF provides grounding for further investigation into a possible regional-scale hydrothermal event at least re-constituting the ores. Some shortcomings in previous works include disregard for the highly variable nature of the PMF deposits, the effects of hydrothermal activity of the ores and the existence of stratigraphic discrepancies. This study provides a single, broad model for the development of all manganese deposits of the PMF. The source of metals is attributed to all formations that stratigraphically overly the Reivilo Formation of the Campbellrand Subgroup (including the Reivilo Formation itself). The main process by which metals are accumulated is attributed to karstification of the dolomites. The interaction of oxidized, alkaline brines with the ores is considered and the overlying Asbestos Hills Subgroup BIF is suggested as a potential source of alkali metals.
- Full Text:
- Date Issued: 2014
Gold mineralisation at Masumbi Au-Cu Prospect, west Kenya : implication for gold exploration in the Archaean Ndori Greenstone Belt of Kenya
- Authors: Salimo, Luckmore
- Date: 2014
- Subjects: Gold mines and mining -- Kenya -- Nyanza Province , Copper -- Kenya -- Nyanza Province , Prospecting -- Kenya -- Nyanza Province , Chalcopyrite -- Kenya -- Nyanza Province , Metamorphism (Geology) , Geochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5096 , http://hdl.handle.net/10962/d1020961
- Description: The Masumbi Au-Cu deposit in the Ndori Greenstone Belt of western Kenya is hosted in dacitic volcanics of the Nyanzian Group (2710 ± 340 Ma) and dioritic to granodioritic felsic intrusives (2504 ± 48 Ma). The deposit is characterised by gold and copper mineralisation that is associated with quartz-sulphide veins and veinlets. The copper mineralisation typically occurs as chalcopyrite. Gold is closely associated with pyrite in mineralogy and its pathfinder elements silver, bismuth, tellurium and selenium in geochemistry. The gold occurs in two forms that may indicate two generations of precipitation: the equant and the elongate forms. Based on Au/Ag ratios, the equant gold grains can be classified as native gold as their gold content is greater than 90 wt%. The elongate gold grains can be classified as electrums as their silver content is greater than 38 wt%. While there is a strong Au-Ag association within individual gold grains supporting an orogenic model for the gold mineralisation, mineralisation at the Masumbi Prospect appears atypical of Archaean orogenic gold deposits because of the abundance of copper (up to 0.43%). The enrichment of silver, copper, bismuth and tellurium in ore assemblages is common in porphyry, VMS and epithermal systems, but their presence at Masumbi does not preclude the formation as an orogenic deposit. Assay results from three Masumbi diamond drill-holes show an apparent correlation between gold and copper. However, petrography and electron probe microanalyses results from this study indicate that chalcopyrite is an earlier phase than pyrite as it occasionally occurs as inclusions in pyrite. This petrogenetic relationship between pyrite and chalcopyrite suggests that there is no temporal relationship between gold and copper mineralisation. Statistical analysis of the assays shows no linear correlation between gold and copper thereby supporting the above findings. The gold and copper mineralisation have been interpreted as forming as two separate events with copper forming first followed by gold. These events are both related to the intrusion of the felsic rocks that are associated with the Aruan metamorphic event that has been responsible for the bulk of the gold mineralisation on the Tanzanian Craton. The common alteration assemblage in the Masumbi rocks comprises chlorite and epidote. This alteration assemblage is typical of regional greenschist metamorphic facies grading into amphibolite metamorphic facies in the Nyanzian Group of Kenya. However, these alteration minerals could possibly be products of propylitic alteration in the rock groundmass. Other alteration mineral assemblages, possibly of hydrothermal origin, comprise muscovite, sericite, quartz, carbonate, associated with the sulphides pyrite and chalcopyrite. Although the occurrence of gold appears to be controlled by the presence of pyrite, it is also associated with silicification. Exploration methods have been proposed to target undiscovered gold deposits in the Ndori Greenstone Belt that are similar to the Masumbi deposit. These methods could probably be applied to vein-type gold deposits in other granite-greenstone terranes in the Lake Victoria Goldfields.
- Full Text:
- Date Issued: 2014
- Authors: Salimo, Luckmore
- Date: 2014
- Subjects: Gold mines and mining -- Kenya -- Nyanza Province , Copper -- Kenya -- Nyanza Province , Prospecting -- Kenya -- Nyanza Province , Chalcopyrite -- Kenya -- Nyanza Province , Metamorphism (Geology) , Geochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5096 , http://hdl.handle.net/10962/d1020961
- Description: The Masumbi Au-Cu deposit in the Ndori Greenstone Belt of western Kenya is hosted in dacitic volcanics of the Nyanzian Group (2710 ± 340 Ma) and dioritic to granodioritic felsic intrusives (2504 ± 48 Ma). The deposit is characterised by gold and copper mineralisation that is associated with quartz-sulphide veins and veinlets. The copper mineralisation typically occurs as chalcopyrite. Gold is closely associated with pyrite in mineralogy and its pathfinder elements silver, bismuth, tellurium and selenium in geochemistry. The gold occurs in two forms that may indicate two generations of precipitation: the equant and the elongate forms. Based on Au/Ag ratios, the equant gold grains can be classified as native gold as their gold content is greater than 90 wt%. The elongate gold grains can be classified as electrums as their silver content is greater than 38 wt%. While there is a strong Au-Ag association within individual gold grains supporting an orogenic model for the gold mineralisation, mineralisation at the Masumbi Prospect appears atypical of Archaean orogenic gold deposits because of the abundance of copper (up to 0.43%). The enrichment of silver, copper, bismuth and tellurium in ore assemblages is common in porphyry, VMS and epithermal systems, but their presence at Masumbi does not preclude the formation as an orogenic deposit. Assay results from three Masumbi diamond drill-holes show an apparent correlation between gold and copper. However, petrography and electron probe microanalyses results from this study indicate that chalcopyrite is an earlier phase than pyrite as it occasionally occurs as inclusions in pyrite. This petrogenetic relationship between pyrite and chalcopyrite suggests that there is no temporal relationship between gold and copper mineralisation. Statistical analysis of the assays shows no linear correlation between gold and copper thereby supporting the above findings. The gold and copper mineralisation have been interpreted as forming as two separate events with copper forming first followed by gold. These events are both related to the intrusion of the felsic rocks that are associated with the Aruan metamorphic event that has been responsible for the bulk of the gold mineralisation on the Tanzanian Craton. The common alteration assemblage in the Masumbi rocks comprises chlorite and epidote. This alteration assemblage is typical of regional greenschist metamorphic facies grading into amphibolite metamorphic facies in the Nyanzian Group of Kenya. However, these alteration minerals could possibly be products of propylitic alteration in the rock groundmass. Other alteration mineral assemblages, possibly of hydrothermal origin, comprise muscovite, sericite, quartz, carbonate, associated with the sulphides pyrite and chalcopyrite. Although the occurrence of gold appears to be controlled by the presence of pyrite, it is also associated with silicification. Exploration methods have been proposed to target undiscovered gold deposits in the Ndori Greenstone Belt that are similar to the Masumbi deposit. These methods could probably be applied to vein-type gold deposits in other granite-greenstone terranes in the Lake Victoria Goldfields.
- Full Text:
- Date Issued: 2014
The petrology and geochemistry of the lower pyroxenite succession of the Great Dyke in the Mutorashanga area
- Mason-Apps, Alexander Dymoke
- Authors: Mason-Apps, Alexander Dymoke
- Date: 1998
- Subjects: Petrology , Geochemistry , Dikes (Geology) , Dikes (Geology) -- Zimbabwe
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4990 , http://hdl.handle.net/10962/d1005602 , Petrology , Geochemistry , Dikes (Geology) , Dikes (Geology) -- Zimbabwe
- Description: This thesis focuses on the petrology and geochemistry of the lower Pyroxenite Succession of the Great Dyke of Zimbabwe in an area to the south ofMutorashanga. Particular emphasis is placed upon the economically important chromitite C5, and on the pervasive serpentinization of olivinerich rocks. An overview of the Great Dyke, including the Satellite Dykes, the structure and stratigraphy of the Great Dyke, the economic resources of the Great Dyke, and the evolution of the Great Dyke magma, is given. A review of the geodynamic history of the Zimbabwe Archaean craton, which culminated in widespread cratonisation and emplacement of the Great Dyke is also provided. The silicate rocks of the lower Pyroxenite Succession are highly adcumulate dunites and orthopyroxenites, with well-developed granular textures and a restricted mineral assemblage of olivine and pyroxene, with very minor plagioclase and clinopyroxene. Within cyclic units, the silicate rocks commonly display a textural and modal progression from granular dunite through poikilitic harzburgite, granular harzburgite, and olivine orthopyroxenite, to granular orthopyroxenite. Chromitites commonly occur at the base of each cyclic unit, these are thin, massive, coarse-grained layers, and are shown to be modified, texturally and compositionally, by postcumulus annealing processes. The olivine-rich rocks are pervasively serpentinized to a depth of over 300 metres. The serpentites typically display well-developed pseudomorphic mesh textures, with a slight overprint of nonpseudomorphic interpenetrating textures and late-stage cross-cutting veins. X-Ray diffraction studies indicate that chrysotile is the dominant serpentine mineral, and also reveal the presence of a nickeliferous magnesium hydroxide, occurring as an intimate admixture with serpentine, and believed to be a nickel-bearing analogue of brucite. Mineral and whole rock compositions of chromitite and silicate rocks highlight the strongly magnesian nature of the Ultramafic Sequence. Studies ofthe footwall chromites below chromitite C5 are consistant with a model of replenishment of primitive magma into the Great Dyke magma chamber, at the base of each cyclic unit. The magma injection and subsequent mixing with the evolved resident magma gives rise to chromitite fonnation, and a causes a reversal of the fractionation trend, resulting in a return to more primitive compositions in the silicate rocks. The silicates display an overall fractionation trend that reflects the evolving composition of the parental magma.
- Full Text:
- Date Issued: 1998
- Authors: Mason-Apps, Alexander Dymoke
- Date: 1998
- Subjects: Petrology , Geochemistry , Dikes (Geology) , Dikes (Geology) -- Zimbabwe
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4990 , http://hdl.handle.net/10962/d1005602 , Petrology , Geochemistry , Dikes (Geology) , Dikes (Geology) -- Zimbabwe
- Description: This thesis focuses on the petrology and geochemistry of the lower Pyroxenite Succession of the Great Dyke of Zimbabwe in an area to the south ofMutorashanga. Particular emphasis is placed upon the economically important chromitite C5, and on the pervasive serpentinization of olivinerich rocks. An overview of the Great Dyke, including the Satellite Dykes, the structure and stratigraphy of the Great Dyke, the economic resources of the Great Dyke, and the evolution of the Great Dyke magma, is given. A review of the geodynamic history of the Zimbabwe Archaean craton, which culminated in widespread cratonisation and emplacement of the Great Dyke is also provided. The silicate rocks of the lower Pyroxenite Succession are highly adcumulate dunites and orthopyroxenites, with well-developed granular textures and a restricted mineral assemblage of olivine and pyroxene, with very minor plagioclase and clinopyroxene. Within cyclic units, the silicate rocks commonly display a textural and modal progression from granular dunite through poikilitic harzburgite, granular harzburgite, and olivine orthopyroxenite, to granular orthopyroxenite. Chromitites commonly occur at the base of each cyclic unit, these are thin, massive, coarse-grained layers, and are shown to be modified, texturally and compositionally, by postcumulus annealing processes. The olivine-rich rocks are pervasively serpentinized to a depth of over 300 metres. The serpentites typically display well-developed pseudomorphic mesh textures, with a slight overprint of nonpseudomorphic interpenetrating textures and late-stage cross-cutting veins. X-Ray diffraction studies indicate that chrysotile is the dominant serpentine mineral, and also reveal the presence of a nickeliferous magnesium hydroxide, occurring as an intimate admixture with serpentine, and believed to be a nickel-bearing analogue of brucite. Mineral and whole rock compositions of chromitite and silicate rocks highlight the strongly magnesian nature of the Ultramafic Sequence. Studies ofthe footwall chromites below chromitite C5 are consistant with a model of replenishment of primitive magma into the Great Dyke magma chamber, at the base of each cyclic unit. The magma injection and subsequent mixing with the evolved resident magma gives rise to chromitite fonnation, and a causes a reversal of the fractionation trend, resulting in a return to more primitive compositions in the silicate rocks. The silicates display an overall fractionation trend that reflects the evolving composition of the parental magma.
- Full Text:
- Date Issued: 1998
Petrology and geochemistry of the lower group chromitites and host rocks on the farm Zandspruit 168 JP, Western Bushveld Complex
- Authors: Botha, Michael James
- Date: 1988
- Subjects: Petrology -- Africa, Southern , Geochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4905 , http://hdl.handle.net/10962/d1001565
- Description: The eight Lower Group chromitite layers of the Ruighoek Pyroxenite in the area west of the Pilanesberg (LGl - LG7), on the farm Zandspruit 168 JP, were sampled in borehole cores drilled through the succession. The stratigraphic succession faIls within Cameron's (980) units B to E of the Critical Zone. The lowermost layer of the Lower Group, the LG 1 chromitite, is located some 440 metres below the MG 2 (Middle Group) chromitite layer, above which the first appearance of cumulus plagioclase in the Complex is seen. By convention, this horizon is designated the top of the Ruighoek Pyroxenite in the Western Bushveld Complex. Homogeneous units of chromite-bearing orthopyroxenite (bronzitite), exhibiting inconspicuous layering defined in terms of variations in orthopyroxene grain-size host all but one of the Lower Group layers; the LG 4 chromitite layer is exposed within an olivine-rich subunit 23 metres in thickness (C₃ subunit). The cumulative thickness of chromitite is 2,92 metres or 0,8 per cent of the studied section, which is 381 metres in thickness. Minimum and maximum thicknesses of the LGl - LG7 layers exposed in drill core are 17 and 81 centimetres, respectively, with minor chromitite layers ranging between 2 and 5 centimetres in thickness. Weighted mean Cr₂0₃ contents of units B to E vary between 1,17 and 3,22 per cent, with the latter estimate representative of the D₂ subunit which hosts the LG 6 chromitite layer. The LG 6 is correlated with the Steelpoort layer of the Eastern Bushveld Complex, and varies between 76 and 81 centimetres in thickness under a large portion of the farm Zandspruit. An undisturbed succession striking N15°E and dipping 12 - 15°E is depicted within the studied area, which is bounded on the eastern side by the north-striking Frank fault. Major folding of the layered succession is evident to the north of the area, where the layering adjacent to the trace of the fault dips 35° to the southwest. Particular attention is paid in the present study to (a) the nature of chromitite layers and their host rocks, (b) the contrast between the mineral chemistry of weakly disseminated chromite and grains within massive ore layers, (c) concentrations of Cr, V, Ni, Co, Sc and Ti in orthopyroxene in relation to stratigraphic height, and levels of Sr, Ba and Zr associated with hypothetically pure, intercumulus plagioclase feldspar, and (d) possible mechanisms which induce crystallization of chromitite layers containing 50 per cent Cr₂0₃ from magma with a Cr content of less than 1 000 ppm. Electron microprobe studies of chromite in relation to mineralogical and textural environment clearly reveal that (a) the proportions of Cr and Al cations are linked to paragenesis: higher Al/Cr ratios characterize olivine-bearing domains, whereas grains intergrown with plagioclase feldspar exhibit low AI/Cr ratios, and (b) Al contents rise with a decline in Mg/(Mg + Fe²⁺) from high values to a value of 0,450, then decrease with a further decline in Mg/(Mg + Fe²⁺). The paragenetically later trend is emphasized in a large population of chromite grains which escaped early encapsulation in orthopyroxene crystals and continued to grow in the environment of intercumulus plagioclase. Within-and between-sample compositional variation of grains in silicate-rich domains is modelled in terms of in situ growth increments, diffusive homogenization of zonal structures, and residence time within interstitial melt. Fractionation trends, as measured by Mg/(Mg + Fe²⁺) ratios in whole-rock and/or microprobe studies of orthopyroxene, are reversed in relation to stratigraphic height towards the top of the B unit and in the overlying C unit. These data are supported, for example, by lower vanadium contents and higher Ni/Sc ratios in hypothetically pure orthopyroxene. Small olivine crystals in chromite-rich domains are enriched in Ni relative to coarse-grained olivine in adjacent dunite: a feature attributed to early isolation of primocrysts from magma in the former case, and in situ equilibration between olivine crystals and Ni-depleted residual melt in the latter case . Similarly, rising Ni contents and Mg/(Mg + Fe²⁺) ratios of orthopyroxene with increasing stratigraphic height in the footwall of the LG 6 chromitite layer, linked to a progressive decline in orthopyroxene grain-size, are effects which may arise out of early separation of interstitial melt from orthopyroxene cumulates. A model is thus proposed which (a) links the thickness of chromitite layers to the vertical separation between successive layers or the thickness of fine-grained orthopyroxenite in the footwall, (b) ascribes copious nucleation of chromite to liquid mixing of this footwall derived, Cr - depleted contaminant with influxes of hot, primitive magma, and (c) tenders the notion that the present modal proportion of mesostasis in the footwall of a chromitite layer serves as a reciprocal measure of the volume of fractionated exudate
- Full Text:
- Date Issued: 1988
- Authors: Botha, Michael James
- Date: 1988
- Subjects: Petrology -- Africa, Southern , Geochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4905 , http://hdl.handle.net/10962/d1001565
- Description: The eight Lower Group chromitite layers of the Ruighoek Pyroxenite in the area west of the Pilanesberg (LGl - LG7), on the farm Zandspruit 168 JP, were sampled in borehole cores drilled through the succession. The stratigraphic succession faIls within Cameron's (980) units B to E of the Critical Zone. The lowermost layer of the Lower Group, the LG 1 chromitite, is located some 440 metres below the MG 2 (Middle Group) chromitite layer, above which the first appearance of cumulus plagioclase in the Complex is seen. By convention, this horizon is designated the top of the Ruighoek Pyroxenite in the Western Bushveld Complex. Homogeneous units of chromite-bearing orthopyroxenite (bronzitite), exhibiting inconspicuous layering defined in terms of variations in orthopyroxene grain-size host all but one of the Lower Group layers; the LG 4 chromitite layer is exposed within an olivine-rich subunit 23 metres in thickness (C₃ subunit). The cumulative thickness of chromitite is 2,92 metres or 0,8 per cent of the studied section, which is 381 metres in thickness. Minimum and maximum thicknesses of the LGl - LG7 layers exposed in drill core are 17 and 81 centimetres, respectively, with minor chromitite layers ranging between 2 and 5 centimetres in thickness. Weighted mean Cr₂0₃ contents of units B to E vary between 1,17 and 3,22 per cent, with the latter estimate representative of the D₂ subunit which hosts the LG 6 chromitite layer. The LG 6 is correlated with the Steelpoort layer of the Eastern Bushveld Complex, and varies between 76 and 81 centimetres in thickness under a large portion of the farm Zandspruit. An undisturbed succession striking N15°E and dipping 12 - 15°E is depicted within the studied area, which is bounded on the eastern side by the north-striking Frank fault. Major folding of the layered succession is evident to the north of the area, where the layering adjacent to the trace of the fault dips 35° to the southwest. Particular attention is paid in the present study to (a) the nature of chromitite layers and their host rocks, (b) the contrast between the mineral chemistry of weakly disseminated chromite and grains within massive ore layers, (c) concentrations of Cr, V, Ni, Co, Sc and Ti in orthopyroxene in relation to stratigraphic height, and levels of Sr, Ba and Zr associated with hypothetically pure, intercumulus plagioclase feldspar, and (d) possible mechanisms which induce crystallization of chromitite layers containing 50 per cent Cr₂0₃ from magma with a Cr content of less than 1 000 ppm. Electron microprobe studies of chromite in relation to mineralogical and textural environment clearly reveal that (a) the proportions of Cr and Al cations are linked to paragenesis: higher Al/Cr ratios characterize olivine-bearing domains, whereas grains intergrown with plagioclase feldspar exhibit low AI/Cr ratios, and (b) Al contents rise with a decline in Mg/(Mg + Fe²⁺) from high values to a value of 0,450, then decrease with a further decline in Mg/(Mg + Fe²⁺). The paragenetically later trend is emphasized in a large population of chromite grains which escaped early encapsulation in orthopyroxene crystals and continued to grow in the environment of intercumulus plagioclase. Within-and between-sample compositional variation of grains in silicate-rich domains is modelled in terms of in situ growth increments, diffusive homogenization of zonal structures, and residence time within interstitial melt. Fractionation trends, as measured by Mg/(Mg + Fe²⁺) ratios in whole-rock and/or microprobe studies of orthopyroxene, are reversed in relation to stratigraphic height towards the top of the B unit and in the overlying C unit. These data are supported, for example, by lower vanadium contents and higher Ni/Sc ratios in hypothetically pure orthopyroxene. Small olivine crystals in chromite-rich domains are enriched in Ni relative to coarse-grained olivine in adjacent dunite: a feature attributed to early isolation of primocrysts from magma in the former case, and in situ equilibration between olivine crystals and Ni-depleted residual melt in the latter case . Similarly, rising Ni contents and Mg/(Mg + Fe²⁺) ratios of orthopyroxene with increasing stratigraphic height in the footwall of the LG 6 chromitite layer, linked to a progressive decline in orthopyroxene grain-size, are effects which may arise out of early separation of interstitial melt from orthopyroxene cumulates. A model is thus proposed which (a) links the thickness of chromitite layers to the vertical separation between successive layers or the thickness of fine-grained orthopyroxenite in the footwall, (b) ascribes copious nucleation of chromite to liquid mixing of this footwall derived, Cr - depleted contaminant with influxes of hot, primitive magma, and (c) tenders the notion that the present modal proportion of mesostasis in the footwall of a chromitite layer serves as a reciprocal measure of the volume of fractionated exudate
- Full Text:
- Date Issued: 1988
Economic geology of sulphide nickel deposits
- Authors: Harrison, P A
- Date: 1983
- Subjects: Nickel sulfide , Ore deposits , Geology, Economic , Silicate minerals , Geochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5022 , http://hdl.handle.net/10962/d1006349
- Description: From Chapter 1: It has been a long standing belief that many nickel sulphide ores are derivatives of magmatic processes in ultramafic and mafic rocks, and that they segregate from these magmas as immiscible sulphide droplets which are then concentrated into an orebody by gravitational settling either during intrusion or extrusion, or during the early stages of crystallization of the magma (Naldrett, 1981). Some geologists however, have suggested alternative mechanisms to explain the concentration of nickeliferous sulphides in the mafic and ultramafic hosts. These include hydrothermal replacement (Fleet, 1977), exhalative volcanic processes (Lusk, 1976), or major metamorphic upgrading of low grade, initially magmatic deposits (Barrett et al., 1977). It is not the purpose of this study to verify or disprove these hypotheses, but in so far as the initial concentration of sulphides in most deposits is concerned, these effects are relatively unimportant (Naldrett, 1981). The nickel sulphide ores associated with these mafic and ultramafic host rocks, invariably consist of nickeliferous pyrrhotite as the dominant phase, together with lesser, but variable, amounts of magnetite, pentlandite, chalcopyrite, cubanite, and platinum group elements (Reynolds, 1982).
- Full Text:
- Date Issued: 1983
- Authors: Harrison, P A
- Date: 1983
- Subjects: Nickel sulfide , Ore deposits , Geology, Economic , Silicate minerals , Geochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5022 , http://hdl.handle.net/10962/d1006349
- Description: From Chapter 1: It has been a long standing belief that many nickel sulphide ores are derivatives of magmatic processes in ultramafic and mafic rocks, and that they segregate from these magmas as immiscible sulphide droplets which are then concentrated into an orebody by gravitational settling either during intrusion or extrusion, or during the early stages of crystallization of the magma (Naldrett, 1981). Some geologists however, have suggested alternative mechanisms to explain the concentration of nickeliferous sulphides in the mafic and ultramafic hosts. These include hydrothermal replacement (Fleet, 1977), exhalative volcanic processes (Lusk, 1976), or major metamorphic upgrading of low grade, initially magmatic deposits (Barrett et al., 1977). It is not the purpose of this study to verify or disprove these hypotheses, but in so far as the initial concentration of sulphides in most deposits is concerned, these effects are relatively unimportant (Naldrett, 1981). The nickel sulphide ores associated with these mafic and ultramafic host rocks, invariably consist of nickeliferous pyrrhotite as the dominant phase, together with lesser, but variable, amounts of magnetite, pentlandite, chalcopyrite, cubanite, and platinum group elements (Reynolds, 1982).
- Full Text:
- Date Issued: 1983
The factors affecting the interpretation of geochemical surveys in mineral exploration
- Authors: Fletcher, B A
- Date: 1982
- Subjects: Geochemistry , Geochemistry -- Environmental aspects , Mining geology , Minerals , Ore deposits , Geochemical prospecting
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5014 , http://hdl.handle.net/10962/d1006142
- Description: [From introduction] Exploration geochemistry is an indirect method of detecting mineral deposits by measuring the abundance and distribution of ore elements and elements closely associated with ore in natural materials at or near the earth's surface. The method relies on the assumption that a mineral deposit is reflected by unusual element abundances or distribution patterns (geochemical halos), and that these indications of mineralization can be detected by geochemical surveys involving the collection and analysis of natural materials. The interpretation of geochemical surveys in mineral exploration involves: 1) The use of geological and statistical inference, based on a knowledge of the normal behaviour and distribution of indicator elements in the exploration area, to recognize apparent geochemical anomalies in field and analytical data and to predict the type of geochemical halo reflected by the anomalies. 11) The use of geological inference, based on a knowledge of the characteristics of geochemical halos and their relationship to mineral deposits, to predict the presence and probable location of an ore body. The interpretation process is, however, complicated by the absence of a simple universal formula that relates the abundance and distribution of elements in natural materials to the presence or absence of a mineral deposit. The interpretation of a geochemical survey must, thus, be based on an empirical approach which avaluates each survey as an individual problem. The objective of this dissertation is to illustrate the factors affecting the "nuts and bolts" approach to the interpretation of geochemical surveys in mineral exploration. The discussion is aimed at providing field geologists responsible -for the planning and execution of geochemical surveys with some basic guidelines for interpreting the surveys. I hope that the contents of this dissertation will help field geologists to "look in the last place first".
- Full Text:
- Date Issued: 1982
- Authors: Fletcher, B A
- Date: 1982
- Subjects: Geochemistry , Geochemistry -- Environmental aspects , Mining geology , Minerals , Ore deposits , Geochemical prospecting
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5014 , http://hdl.handle.net/10962/d1006142
- Description: [From introduction] Exploration geochemistry is an indirect method of detecting mineral deposits by measuring the abundance and distribution of ore elements and elements closely associated with ore in natural materials at or near the earth's surface. The method relies on the assumption that a mineral deposit is reflected by unusual element abundances or distribution patterns (geochemical halos), and that these indications of mineralization can be detected by geochemical surveys involving the collection and analysis of natural materials. The interpretation of geochemical surveys in mineral exploration involves: 1) The use of geological and statistical inference, based on a knowledge of the normal behaviour and distribution of indicator elements in the exploration area, to recognize apparent geochemical anomalies in field and analytical data and to predict the type of geochemical halo reflected by the anomalies. 11) The use of geological inference, based on a knowledge of the characteristics of geochemical halos and their relationship to mineral deposits, to predict the presence and probable location of an ore body. The interpretation process is, however, complicated by the absence of a simple universal formula that relates the abundance and distribution of elements in natural materials to the presence or absence of a mineral deposit. The interpretation of a geochemical survey must, thus, be based on an empirical approach which avaluates each survey as an individual problem. The objective of this dissertation is to illustrate the factors affecting the "nuts and bolts" approach to the interpretation of geochemical surveys in mineral exploration. The discussion is aimed at providing field geologists responsible -for the planning and execution of geochemical surveys with some basic guidelines for interpreting the surveys. I hope that the contents of this dissertation will help field geologists to "look in the last place first".
- Full Text:
- Date Issued: 1982
A review of unconformity-type uranium deposits
- Authors: Dabrowski, F A
- Date: 1980 , 2013-04-02
- Subjects: Uranium ores , Mineralogy , Geochemistry , Unconformities (Geology)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4917 , http://hdl.handle.net/10962/d1003289 , Uranium ores , Mineralogy , Geochemistry , Unconformities (Geology)
- Description: Intense interest in uranium in the past decade has led to the discovery of new kinds of deposits of which the so-called unconformity-type are economically the most important. Presently known occurrences are restricted to Australia and Canada where they are characterized chiefly by their spatial relationship to Lower-Middle Proterozoic unconformities. Other common features include similar host-rock assemblages, structural controls, alteration, mineralogy, age relationships and fluid-inclusion data. Similar characteristics in other vein-type deposits, including those of the Beaverlodge district in Canada, deposits in France and Portugal, and the Schwartzwalder mine in the United States, suggest that they may also be of the unconformity-type. Various interpretations of the geological relationships of unconformity-type deposits have resulted in a number of genetic hypotheses, which require different exploration philosophies. Nearsurface supergene processes are considered to be most important although other mechanisms may have played contributing roles in the concentration of uranium. There is considerable potential for further discoveries of unconformity-type uranium deposits throughout the world. No such deposits are yet known in southern Africa although several favourable Precambrian unconformities are present.
- Full Text:
- Date Issued: 1980
- Authors: Dabrowski, F A
- Date: 1980 , 2013-04-02
- Subjects: Uranium ores , Mineralogy , Geochemistry , Unconformities (Geology)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4917 , http://hdl.handle.net/10962/d1003289 , Uranium ores , Mineralogy , Geochemistry , Unconformities (Geology)
- Description: Intense interest in uranium in the past decade has led to the discovery of new kinds of deposits of which the so-called unconformity-type are economically the most important. Presently known occurrences are restricted to Australia and Canada where they are characterized chiefly by their spatial relationship to Lower-Middle Proterozoic unconformities. Other common features include similar host-rock assemblages, structural controls, alteration, mineralogy, age relationships and fluid-inclusion data. Similar characteristics in other vein-type deposits, including those of the Beaverlodge district in Canada, deposits in France and Portugal, and the Schwartzwalder mine in the United States, suggest that they may also be of the unconformity-type. Various interpretations of the geological relationships of unconformity-type deposits have resulted in a number of genetic hypotheses, which require different exploration philosophies. Nearsurface supergene processes are considered to be most important although other mechanisms may have played contributing roles in the concentration of uranium. There is considerable potential for further discoveries of unconformity-type uranium deposits throughout the world. No such deposits are yet known in southern Africa although several favourable Precambrian unconformities are present.
- Full Text:
- Date Issued: 1980
The behaviour of the elements Ni, Co, Cu, Pb, Zn, Au, Ag, Mo, Sn, W and U in the magmatic, hydrothermal, sedimentary and weathering environments
- Authors: Anderson, J R
- Date: 1979
- Subjects: Elements , Environment , Ore deposits , Classification , Geochemistry , Crystal chemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4896 , http://hdl.handle.net/10962/d1001555
- Description: In the last two decades much has been published on the behaviour of certain elements in the magmatic , hydrothermal, sedimentary and weathering environments , but the information is scattered throughout the literature . This situation prompted the present study on the elements Ni, Co, Cu, Pb , Zn , Au, Ag , Mo , Sn, W and U. The behaviour of the elements Ni, Cu, Pb , ZN, Au, Sn , W and U has been studied experimentally in some depth. Ag has been moderately studied, but there is very little information about Co and Mo. Studies on the complexes formed by the elements within the hydrothermal and aqueous environment are often inconclusive and controversial , but conclusions are drawn as to the more likely complexes formed . A genetic classification of ore deposits is used as a framework for the discussion . The source of the elements is regarded as being the mantle, and therefore discussion on other possible sources is beyond the scope of this dissertation. The crystal chemistry and geochemistry of the elements are presented and the essay concludes with a discussion on the elements within their depositional environments
- Full Text:
- Date Issued: 1979
- Authors: Anderson, J R
- Date: 1979
- Subjects: Elements , Environment , Ore deposits , Classification , Geochemistry , Crystal chemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4896 , http://hdl.handle.net/10962/d1001555
- Description: In the last two decades much has been published on the behaviour of certain elements in the magmatic , hydrothermal, sedimentary and weathering environments , but the information is scattered throughout the literature . This situation prompted the present study on the elements Ni, Co, Cu, Pb , Zn , Au, Ag , Mo , Sn, W and U. The behaviour of the elements Ni, Cu, Pb , ZN, Au, Sn , W and U has been studied experimentally in some depth. Ag has been moderately studied, but there is very little information about Co and Mo. Studies on the complexes formed by the elements within the hydrothermal and aqueous environment are often inconclusive and controversial , but conclusions are drawn as to the more likely complexes formed . A genetic classification of ore deposits is used as a framework for the discussion . The source of the elements is regarded as being the mantle, and therefore discussion on other possible sources is beyond the scope of this dissertation. The crystal chemistry and geochemistry of the elements are presented and the essay concludes with a discussion on the elements within their depositional environments
- Full Text:
- Date Issued: 1979
The geochemistry and petrology of the Karoo andesites and associated basalts of the north-eastern Cape Province
- Authors: Rumble, Keith Christopher
- Date: 1979 , 2013-02-11
- Subjects: Basalt , South Africa , Cape of Good Hope , Geochemistry , Petrology , Andesite
- Language: English
- Type: Thesis , Masters , M.Sc
- Identifier: vital:4902 , http://hdl.handle.net/10962/d1001562
- Description: New geochemical data consisting of major and 15 trace element analyses are presented for 41 rocks from three andesitic and associated basaltic rock occurrences in the North Eastern Cape Province. These include the Pronksberg, Belmore and Roodehoek localities. Field evidence suggests that the three andesites were emplaced during the early stages of Karoo volcanicity. Geochemical variations within the Pronksberg and Roodehoek andesite are small, manifesting the undifferentiated nature of the magmas. Variations within the Belmore andesite are interpreted as representing fractionation of orthopyroxene, accompanied by only minor plagioclase fractionation. Differences in trace element concentrations and inter-element ratios between the andesites and associated basalts of the Pronksberg and Belmore volcanic suites precludes the possibility of the two rock types being genetically related. Geochemical differences constrain the possibility of the three andesites being cogenetic. Magmatic processes resulting in their formation are, however, thought to be similar. The differences in chemistry between the Pronksberg Basalt (High K Type) and Pronksberg Basalt (Drumbo Type) are interpreted as representing the combined influence of weathering, the presence of amygdales and the within-flow variations of alkali elements on the Pronksberg Basalt (High K Type). Similarities in petrography and chemistry justifies a correlation of the Pronksberg Basalt (Drumbo Type) with the Drumbo Basalt Member in the Barkly East area. Data for the Drumbo Basalt (This study) in the Barkly East area confirms and complements previously presented data. Normative chemistry and strontium isotope data indicate a process involving crustal assimilation or melting of crustal rocks as being the most likely explanation for the genesis of the Karoo andesites , KMBT_363 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 1979
- Authors: Rumble, Keith Christopher
- Date: 1979 , 2013-02-11
- Subjects: Basalt , South Africa , Cape of Good Hope , Geochemistry , Petrology , Andesite
- Language: English
- Type: Thesis , Masters , M.Sc
- Identifier: vital:4902 , http://hdl.handle.net/10962/d1001562
- Description: New geochemical data consisting of major and 15 trace element analyses are presented for 41 rocks from three andesitic and associated basaltic rock occurrences in the North Eastern Cape Province. These include the Pronksberg, Belmore and Roodehoek localities. Field evidence suggests that the three andesites were emplaced during the early stages of Karoo volcanicity. Geochemical variations within the Pronksberg and Roodehoek andesite are small, manifesting the undifferentiated nature of the magmas. Variations within the Belmore andesite are interpreted as representing fractionation of orthopyroxene, accompanied by only minor plagioclase fractionation. Differences in trace element concentrations and inter-element ratios between the andesites and associated basalts of the Pronksberg and Belmore volcanic suites precludes the possibility of the two rock types being genetically related. Geochemical differences constrain the possibility of the three andesites being cogenetic. Magmatic processes resulting in their formation are, however, thought to be similar. The differences in chemistry between the Pronksberg Basalt (High K Type) and Pronksberg Basalt (Drumbo Type) are interpreted as representing the combined influence of weathering, the presence of amygdales and the within-flow variations of alkali elements on the Pronksberg Basalt (High K Type). Similarities in petrography and chemistry justifies a correlation of the Pronksberg Basalt (Drumbo Type) with the Drumbo Basalt Member in the Barkly East area. Data for the Drumbo Basalt (This study) in the Barkly East area confirms and complements previously presented data. Normative chemistry and strontium isotope data indicate a process involving crustal assimilation or melting of crustal rocks as being the most likely explanation for the genesis of the Karoo andesites , KMBT_363 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 1979
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